Comparison of rapid methods for analysis of bacterial fatty acids

Appl Microbiol. 1974 Jul;28(1):80-5. doi: 10.1128/am.28.1.80-85.1974.

Abstract

When rapid gas-liquid chromatography methods for determination of bacterial fatty acids were compared, results showed that saponification was required for total fatty acid analysis. Transesterification with boron-trihalide reagents (BF(3)-CH(3)OH, BCl(3)-CH(3)OH) caused extensive degradation of cyclopropane acids and was less effective than saponification in releasing cellular hydroxy fatty acids. Digestion of cells with tetramethylammonium hydroxide was unsatisfactory because of extraneous gas-liquid chromatography peaks and because of lower recovery of branched-chain and hydroxy fatty acids. A simple, rapid saponification procedure which can be used for total cellular fatty acid analysis of freshly grown cells is described.

Publication types

  • Comparative Study

MeSH terms

  • Boron Compounds
  • Chromatography, Gas
  • Esters / analysis
  • Fatty Acids / analysis*
  • Freeze Drying
  • Indicators and Reagents*
  • Methods
  • Pseudomonas / analysis*
  • Quaternary Ammonium Compounds

Substances

  • Boron Compounds
  • Esters
  • Fatty Acids
  • Indicators and Reagents
  • Quaternary Ammonium Compounds