Mg2+- or Mn2+-dependent p-nitrophenylphosphatase activity is present in Ehrlich ascites tumor cells

Arch Biochem Biophys. 1984 Jul;232(1):214-22. doi: 10.1016/0003-9861(84)90537-x.

Abstract

The presence of a soluble, Mg2+- or Mn2+-dependent p-nitrophenylphosphatase activity in Ehrlich ascites tumor cell homogenates is reported. The crude homogenate was fractionated over Sephadex G-150 gel-filtration and DEAE-Sephacel anion-exchange columns, and two p-nitrophenylphosphatase activities were resolved. The most active fraction, Peak I, was characterized and found to be similar to phosphotyrosyl-protein phosphatases characterized elsewhere in that it has optimal activity at neutral pH; it is inhibited by phosphate, Zn2+, and vanadate; and it is not inhibited by levamisole. However, Peak I differs from phosphotyrosyl-protein phosphatases in that Mg2+ or Mn2+ is required for activity, fluoride is an inhibitor, and pyrophosphate is not inhibitory. Inhibition by the phosphorylated compounds phosphotyrosine, phosphoserine, phosphothreonine, ATP, CTP, GTP, ITP, NADP, fructose 6-phosphate, glucose 1-phosphate, galactose 1-phosphate, 2-phosphogluconic acid, and 6-phosphogluconic acid was also observed. Ehrlich ascites tumor cell p-nitrophenylphosphatase is shown to be sensitive to inactivation by trypsin, N-ethylmaleimide, or heat treatments.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • 4-Nitrophenylphosphatase / antagonists & inhibitors
  • 4-Nitrophenylphosphatase / metabolism*
  • Animals
  • Carcinoma, Ehrlich Tumor / enzymology*
  • Chromatography, Gel
  • Ethylmaleimide / pharmacology
  • Hot Temperature
  • Hydrogen-Ion Concentration
  • Magnesium / metabolism*
  • Male
  • Manganese / metabolism*
  • Mice
  • Mice, Inbred Strains
  • Phosphoric Monoester Hydrolases / metabolism*
  • Phosphorylation
  • Substrate Specificity
  • Trypsin / pharmacology

Substances

  • Manganese
  • Phosphoric Monoester Hydrolases
  • 4-Nitrophenylphosphatase
  • Trypsin
  • Magnesium
  • Ethylmaleimide