Role of gamma-glutamyltransferase in putrescine uptake by rat type II pneumocytes

Biochem Pharmacol. 1995 Sep 28;50(7):981-9. doi: 10.1016/0006-2952(95)00223-m.

Abstract

Putrescine uptake in type II pneumocytes is a carrier-mediated active process. Our hypothesis was that oligoamines might be taken up into the cell at least in part by gamma-glutamyltransferase (gamma-GT). This was investigated in rat type II pneumocytes 24 hr after their isolation. Preexposure to 125 microM L-buthionine-[SR]-sulfoximine (BSO) or 100 microM diethylmaleate (DEM), both of which affect intracellular glutathione (GSH) only, were found to decrease GSH by 85% (p < 0.05) and 62%, respectively (p < 0.05), without change in [3H]-putrescine uptake. Preexposure to 20 microM N-ethylmaleimide (NEM), which affects intra- and extracellular GSH, decreased intracellular GSH by 79% (p = 0.015) and putrescine uptake by 39% (p = 0.03). Selective extracellular GSH depletion by 10 microM copper-o-phenanthroline complex (CuP) led to a decrease in putrescine uptake of 41% (p = 0.001), while intracellular GSH remained unchanged. Specific inhibition of gamma-GT by 5-20 mM serine-borate or 5 mM acivicin gave similar degrees of putrescine uptake inhibition (39.5% and 40.5%). The kinetic properties of the putrescine uptake system in the presence of acivicin and serine-borate indicated that the Vmax decreased by 25%, while Km remained unchanged. In experiments with pure gamma-GT, the oligoamines putrescine, spermidine and spermine, and cystamine proved to be acceptor substrates for gamma-GT, all having similar efficiencies (Vmax/Km); methylglyoxal-bis-(guanyl-hydrazone) and paraquat were not accepted. As extracellular GSH is required for gamma-GT, and because its extracellular depletion inhibits putrescine uptake as much as specific inhibition of gamma-GT, we suggest that 30-40% of the putrescine uptake in type II pneumocytes occurs by gamma-GT and that, therefore, at least two systems are involved in the uptake of putrescine.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Borates / pharmacology
  • Cell Separation
  • Cell Survival
  • Cells, Cultured
  • Copper
  • Down-Regulation
  • Glutathione / metabolism
  • Glutathione / pharmacology
  • Isoxazoles / pharmacology
  • Kinetics
  • Lung / metabolism*
  • Male
  • Organometallic Compounds / pharmacology
  • Phenanthrolines / pharmacology
  • Putrescine / metabolism*
  • Rats
  • Rats, Wistar
  • Serine / pharmacology
  • gamma-Glutamyltransferase / antagonists & inhibitors
  • gamma-Glutamyltransferase / metabolism*

Substances

  • Borates
  • Isoxazoles
  • Organometallic Compounds
  • Phenanthrolines
  • serine-borate complex
  • bis(1,10-phenanthroline)copper(2+) ion
  • Serine
  • Copper
  • gamma-Glutamyltransferase
  • Glutathione
  • acivicin
  • Putrescine