Structure of 3 beta-hydroxy-16-oxo-24-nor-17-azachol-5-eno-23-nitrile and its 20S epimer

Steroids. 1995 Feb;60(2):195-203. doi: 10.1016/0039-128x(94)00037-d.

Abstract

The structures of the title compounds have been investigated in solid state by X-ray and in solution by NMR methods. The configurations at C20 and the preferred conformations of both epimers were established. A full assignment of signals in 1H and 13C NMR spectra was done.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aza Compounds / chemistry*
  • Carbon Isotopes
  • Crystallography, X-Ray*
  • Magnetic Resonance Spectroscopy*
  • Models, Molecular
  • Norsteroids / chemistry*
  • Protons
  • Stereoisomerism

Substances

  • 3-hydroxy-16-oxo-24-nor-17-azachol-5-eno-23-nitrile
  • Aza Compounds
  • Carbon Isotopes
  • Norsteroids
  • Protons