A disaccharide that inhibits tumor necrosis factor alpha is formed from the extracellular matrix by the enzyme heparanase

Proc Natl Acad Sci U S A. 1995 May 23;92(11):5037-41. doi: 10.1073/pnas.92.11.5037.

Abstract

The activation of T cells by antigens or mitogens leads to the secretion of cytokines and enzymes that shape the inflammatory response. Among these molecular mediators of inflammation is a heparanase enzyme that degrades the heparan sulfate scaffold of the extracellular matrix (ECM). Activated T cells use heparanase to penetrate the ECM and gain access to the tissues. We now report that among the breakdown products of the ECM generated by heparanase is a trisulfated disaccharide that can inhibit delayed-type hypersensitivity (DTH) in mice. This inhibition of T-cell mediated inflammation in vivo was associated with an inhibitory effect of the disaccharide on the production of biologically active tumor necrosis factor alpha (TNF-alpha) by activated T cells in vitro; the trisulfated disaccharide did not affect T-cell viability or responsiveness generally. Both the in vivo and in vitro effects of the disaccharide manifested a bell-shaped dose-response curve. The inhibitory effects of the trisulfated disaccharide were lost if the sulfate groups were removed. Thus, the disaccharide, which may be a natural product of inflammation, can regulate the functional nature of the response by the T cell to activation. Such a feedback control mechanism could enable the T cell to assess the extent of tissue degradation and adjust its behavior accordingly.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Carbohydrate Sequence
  • Cattle
  • Cell Survival / drug effects
  • Chromatography, Gel
  • Cornea / chemistry
  • Disaccharides / isolation & purification
  • Disaccharides / metabolism*
  • Disaccharides / pharmacology*
  • Endothelium / chemistry
  • Extracellular Matrix / metabolism*
  • Feedback
  • Female
  • Glucuronidase*
  • Glycoside Hydrolases / metabolism*
  • Heparin / pharmacology
  • Hypersensitivity, Delayed / prevention & control*
  • Inflammation
  • Mice
  • Mice, Inbred BALB C
  • Models, Immunological
  • Molecular Sequence Data
  • Spectrometry, Mass, Fast Atom Bombardment
  • T-Lymphocytes / cytology
  • T-Lymphocytes / drug effects
  • T-Lymphocytes / immunology
  • Tumor Necrosis Factor-alpha / antagonists & inhibitors*

Substances

  • Disaccharides
  • Tumor Necrosis Factor-alpha
  • Heparin
  • Glycoside Hydrolases
  • heparanase
  • Glucuronidase