Determination of MK-383, a non-peptide fibrinogen receptor antagonist, in human plasma and urine by radioimmunoassay

J Pharm Biomed Anal. 1994 Aug;12(8):1047-53. doi: 10.1016/0731-7085(94)e0009-p.

Abstract

MK-383 is a novel, non-peptide fibrinogen receptor antagonist. A sensitive and specific radioimmunoassay has been developed for the determination of this drug candidate in plasma and urine. The immunogen was prepared by coupling to albumin via the N-hydroxysuccinimide ester from which the radioligand was also prepared by reaction with [I125]iodotyrosine. The method was specific and no immunoreactive material other than the parent drug was detectable in plasma and urine from dosed volunteers. This direct assay, using 5 microliters of plasma or 0.5 microliter of urine, is sensitive to 1 and 10 ng ml-1, respectively, without matrix interference and has sufficient sensitivity, specificity, accuracy, and precision for the analysis of clinical samples.

MeSH terms

  • Animals
  • Antibody Specificity
  • Female
  • Fibrinolytic Agents / blood*
  • Fibrinolytic Agents / immunology
  • Fibrinolytic Agents / urine*
  • Heparin / chemistry
  • Humans
  • Iodine Radioisotopes
  • Isotope Labeling
  • Platelet Membrane Glycoproteins / antagonists & inhibitors*
  • Rabbits / immunology
  • Radioimmunoassay
  • Tirofiban
  • Tyrosine / analogs & derivatives*
  • Tyrosine / blood
  • Tyrosine / immunology
  • Tyrosine / urine

Substances

  • Fibrinolytic Agents
  • Iodine Radioisotopes
  • Platelet Membrane Glycoproteins
  • Tyrosine
  • Heparin
  • Tirofiban