L-741,494, a fungal metabolite that is an inhibitor of interleukin-1 beta converting enzyme

J Nat Prod. 1994 Jun;57(6):755-60. doi: 10.1021/np50108a011.

Abstract

gamma-Pyrone-3-acetic acid (L-741,494) is a novel metabolite produced by a culture of the fungal genus Xylaria. This substance is a water-soluble, competitive, irreversible inhibitor of Interleukin-1 beta Converting Enzyme that is inactive against papain and trypsin. It has a mol wt of 154 and an empirical formula of C7H6O4. We propose the name xylaric acid for this compound.

MeSH terms

  • Acetates / chemistry
  • Acetates / isolation & purification
  • Acetates / pharmacology*
  • Amino Acid Sequence
  • Caspase 1
  • Chromatography, Ion Exchange
  • Cysteine Endopeptidases / chemistry*
  • Magnetic Resonance Spectroscopy
  • Metalloendopeptidases / chemistry*
  • Molecular Sequence Data
  • Pyrones / chemistry
  • Pyrones / isolation & purification
  • Pyrones / pharmacology*
  • Xylariales / metabolism*

Substances

  • Acetates
  • L 741494
  • Pyrones
  • Cysteine Endopeptidases
  • Caspase 1
  • Metalloendopeptidases