The terminal oxidases of Paracoccus denitrificans

Mol Microbiol. 1994 Jul;13(2):183-96. doi: 10.1111/j.1365-2958.1994.tb00414.x.

Abstract

Three distinct types of terminal oxidases participate in the aerobic respiratory pathways of Paracoccus denitrificans. Two alternative genes encoding subunit I of the aa3-type cytochrome c oxidase have been isolated before, namely ctaDI and ctaDII. Each of these genes can be expressed separately to complement a double mutant (delta ctaDI, delta ctaDII), indicating that they are isoforms of subunit I of the aa3-type oxidase. The genomic locus of a quinol oxidase has been isolated: cyoABC. This protohaem-containing oxidase, called cytochrome bb3, is the only quinol oxidase expressed under the conditions used. In a triple oxidase mutant (delta ctaDI, delta ctaDII, cyoB::KmR) an alternative cytochrome c oxidase has been characterized; this cbb3-type oxidase has been partially purified. Both cytochrome aa3 and cytochrome bb3 are redox-driven proton pumps. The proton-pumping capacity of cytochrome cbb3 has been analysed; arguments for and against the active transport of protons by this novel oxidase complex are discussed.

Publication types

  • Comparative Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aerobiosis
  • Amino Acid Sequence
  • Bacterial Proteins / genetics
  • Bacterial Proteins / isolation & purification*
  • Base Sequence
  • Electron Transport
  • Electron Transport Complex IV / genetics
  • Electron Transport Complex IV / metabolism
  • Genes, Bacterial*
  • Genetic Complementation Test
  • Heme / analysis
  • Operon
  • Oxidoreductases / genetics
  • Oxidoreductases / isolation & purification*
  • Oxygen / metabolism
  • Paracoccus denitrificans / enzymology*
  • Paracoccus denitrificans / genetics
  • Protons
  • Sequence Alignment
  • Sequence Homology, Amino Acid
  • Species Specificity

Substances

  • Bacterial Proteins
  • Protons
  • Heme
  • Oxidoreductases
  • duroquinol oxidase
  • Electron Transport Complex IV
  • Oxygen