Relaxation study of the backbone dynamics of human profilin by two-dimensional 1H-15N NMR

FEBS Lett. 1993 Dec 28;336(3):457-61. doi: 10.1016/0014-5793(93)80855-o.

Abstract

The dynamic properties of 111 backbone HN sites in uncomplexed human profilin, a protein of 139 residues, have been characterized by two-dimensional inverse-detected 1H-15N NMR spectroscopy. Heteronuclear (1H)-15N nuclear Overhauser effects and 15N longitudinal and transverse relaxation rates have been analyzed in terms of model-free spectral density functions and exchange contributions to transverse relaxation rates. Relatively high mobilities on the nanosecond time-scale are observed for Asp26 and Ser27, which form part of a loop connecting beta-strands A and B, and for Thr92 through Ala95, which are in a loop connecting beta-strands E and F. Significant exchange contributions, indicative of motions on the microsecond to millisecond time-scale, have been obtained for 30 residues. These include Leu77, Asp80 and Gly81 of a loop between beta-strands D and E, Ser84 and Met85 of beta-strand E, Gly121 of a loop connecting beta-strand G and the C-terminal helix, and Gln138, which is next to the C-terminal residue Tyr139. Some of the regions showing high flexibility in profilin are known to be involved in poly-L-proline binding.

MeSH terms

  • Amino Acid Sequence
  • Contractile Proteins / chemistry
  • Humans
  • Hydrogen
  • Magnetic Resonance Spectroscopy / methods
  • Mathematics
  • Microfilament Proteins / chemistry*
  • Models, Molecular
  • Nitrogen Isotopes
  • Profilins
  • Protein Folding
  • Protein Structure, Secondary*

Substances

  • Contractile Proteins
  • Microfilament Proteins
  • Nitrogen Isotopes
  • PFN1 protein, human
  • Profilins
  • Hydrogen