The absorption of Fe, Mn, Cu and Cd by charcoal and the influence of pH, particle size and temperature on absorption were studied. A method for the preconcentration of these irons in water was established, and with flame atomic absorption spectroscopy a content as low as microgram/L could be determined. The recovery and the coefficient of variance (n = 6) were in the range of 90-113% and 2.6-9.9%, respectively. The proposed method is simple, rapid, accurate reproducible and suitable for the preconcentration and determination of titled metal irons in different kinds of water.