Abstract
FR901459, a novel immunosuppressant, has been isolated from the fermentation broth of Stachybotrys chartarum No. 19392. The molecular formula of FR901459 was determined as C62H111N11O13. FR901459 was found to be a member of the cyclosporin family. However, it is structurally distinct from any other cyclosporins discovered so far, in that Leu is present at position 5 instead of Val. FR901459 was capable of prolonging the survival time of skin allografts in rats with one third the potency of cyclosporin A.
MeSH terms
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Amino Acid Sequence
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Animals
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Chemical Phenomena
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Chemistry, Physical
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Cyclosporine / biosynthesis
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Cyclosporine / isolation & purification
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Cyclosporine / pharmacology
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Female
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Fermentation
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Fungal Proteins / biosynthesis
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Fungal Proteins / isolation & purification*
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Fungal Proteins / pharmacology*
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Immunosuppressive Agents / isolation & purification*
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Immunosuppressive Agents / metabolism
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Immunosuppressive Agents / pharmacology*
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Magnetic Resonance Spectroscopy
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Mice
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Mice, Inbred BALB C
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Mice, Inbred C57BL
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Molecular Sequence Data
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Molecular Structure
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Stachybotrys / chemistry
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Stachybotrys / classification*
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Stachybotrys / metabolism*
Substances
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Fungal Proteins
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Immunosuppressive Agents
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FR 901459
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Cyclosporine