Purification and characterization of EpiA, the peptide substrate for post-translational modifications involved in epidermin biosynthesis

FEMS Microbiol Lett. 1993 Aug 15;112(1):43-8. doi: 10.1111/j.1574-6968.1993.tb06421.x.

Abstract

For the investigation of enzymes involved in epidermin biosynthesis it is necessary to produce sufficient amounts of preepidermin (EpiA) as a substrate and to design EpiA detection systems. Therefore, EpiA was expressed in Escherichia coli using a malE-epiA fusion. The identity of purified EpiA was confirmed by ion spray mass spectrometry and amino acid sequencing. For EpiA detection, anti-EpiA antisera were raised. Upon prolonged incubation, factor Xa not only cleaved EpiA from the fusion protein, but also less efficiently cleaved EpiA internally between R-1 and I+1. The internal factor Xa cleavage site of EpiA was masked by altering the sequence -A(-4)-E-P-R(-1)- to -A(-4)-E-P-Q(-1)- by site-directed mutagenesis.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Acid Sequence
  • Anti-Bacterial Agents / biosynthesis
  • Bacterial Proteins / genetics
  • Bacterial Proteins / isolation & purification
  • Bacterial Proteins / metabolism*
  • Bacteriocins
  • Endopeptidases / metabolism
  • Escherichia coli / genetics
  • Genes, Bacterial
  • Membrane Proteins*
  • Molecular Sequence Data
  • Peptides*
  • Peptides, Cyclic / biosynthesis
  • Peptides, Cyclic / genetics
  • Protein Precursors / biosynthesis
  • Protein Processing, Post-Translational
  • Protein Sorting Signals / genetics
  • Protein Sorting Signals / metabolism
  • Recombinant Fusion Proteins / genetics
  • Recombinant Fusion Proteins / isolation & purification
  • Serine Endopeptidases*
  • Staphylococcus epidermidis / genetics
  • Staphylococcus epidermidis / metabolism
  • Substrate Specificity

Substances

  • Anti-Bacterial Agents
  • Bacterial Proteins
  • Bacteriocins
  • EpiA protein, Staphylococcus epidermidis
  • Membrane Proteins
  • Peptides
  • Peptides, Cyclic
  • Protein Precursors
  • Protein Sorting Signals
  • Recombinant Fusion Proteins
  • epidermin
  • Endopeptidases
  • Serine Endopeptidases
  • type I signal peptidase