Determination of a HIV protease inhibitor (DMP 450) in animal and human plasma by solid-phase extraction and high-performance liquid chromatography

J Chromatogr B Biomed Appl. 1996 Apr 12;678(2):303-8. doi: 10.1016/0378-4347(95)00478-5.

Abstract

Extraction of DMP 450 from plasma was performed with C2 solid-phase extraction columns, using 0.1 M ammonium acetate in 90% methanol to elute DMP 450. The extraction recovery over the range of 10 to 10 000 ng/ml averaged 81.0, 96.2, 77.4, 95.2 and 68.0% from rat, dog, monkey, chimpanzee (25-10 000 ng/ml) and human plasma, respectively. HPLC analysis was carried out with a C18 column and a mobile phase of acetonitrile, methanol and 30 mM potassium phosphate (pH 3), the composition dependent on the type of plasma being analyzed, and monitored at a wavelength of 229 nm. Intra-day and inter-day coefficients of variation were less than 9.9 and 12.9%, respectively. Absolute differences were less than 11.5%.

MeSH terms

  • Acetonitriles
  • Animals
  • Azepines / blood*
  • Chromatography, High Pressure Liquid / methods*
  • Chromatography, High Pressure Liquid / statistics & numerical data
  • Dogs
  • HIV Protease Inhibitors / blood*
  • Haplorhini
  • Humans
  • Hydrogen-Ion Concentration
  • Methanol
  • Pan troglodytes
  • Phosphates
  • Potassium Compounds
  • Rats
  • Sensitivity and Specificity
  • Urea / analogs & derivatives*
  • Urea / blood

Substances

  • Acetonitriles
  • Azepines
  • HIV Protease Inhibitors
  • Phosphates
  • Potassium Compounds
  • Urea
  • potassium phosphate
  • Methanol
  • DMP 450
  • acetonitrile