High-performance liquid chromatographic methods for the determination of a new carbapenem antibiotic, L-749,345, in human plasma and urine

J Chromatogr B Biomed Sci Appl. 1998 Dec 11;720(1-2):99-106. doi: 10.1016/s0378-4347(98)00437-x.

Abstract

A column-switching, reversed-phase high-performance liquid chromatographic (HPLC) method for the determination of a new carbapenem antibiotic assay using ultraviolet detection has been developed for a new carbapenem antibiotic L-749,345 in human plasma and urine. A plasma sample is centrifuged and then injected onto an extraction column using 25 mM phosphate buffer, pH 6.5. After 3 min, using a column-switching valve, the analyte is back-flushed with 10.5% methanol-phosphate buffer for 3 min onto a Hypersil 5 microm C18 BDS 100x4.6 mm analytical column and then detected by absorbance at 300 nm. The sample preparation and HPLC conditions for the urine assay are similar, except for a longer analytical column 150x4.6 mm. The plasma assay is specific and linear from 0.125 to 50 microg/ml; the urine assay is linear from 1.25 to 100 microg/ml.

MeSH terms

  • Anti-Infective Agents / blood*
  • Anti-Infective Agents / urine*
  • Calibration
  • Carbapenems / blood*
  • Carbapenems / urine*
  • Chromatography, High Pressure Liquid / methods*
  • Humans
  • Reference Standards
  • Reproducibility of Results
  • Spectrophotometry, Ultraviolet

Substances

  • Anti-Infective Agents
  • Carbapenems
  • L 749345