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Unique Single-Atom Binding of Pseudohalogeno Ligands to Four Metal Ions Induced by Their Trapping into High-Nuclearity Cages This work was supported by CICYT (Grant BP96/0163) and the Research Committee of the University of Patras (C. Caratheodory Programme, No 1941).
Papaefstathiou GS, Perlepes SP, Escuer A, Vicente R, Font-Bardia M, Solans X. Papaefstathiou GS, et al. Among authors: perlepes sp. Angew Chem Int Ed Engl. 2001 Mar 2;40(5):884-886. Angew Chem Int Ed Engl. 2001. PMID: 11241635 No abstract available.
Reactivity in polynuclear transition metal chemistry as a means to obtain high-spin molecules: substitution of mu 4-OH- by eta 1,mu 4-N3- increases nine times the ground-state S value of a nonanuclear nickel(II) cage.
Papaefstathiou GS, Escuer A, Vicente R, Font-Bardia M, Solans X, Perlepes SP. Papaefstathiou GS, et al. Among authors: perlepes sp. Chem Commun (Camb). 2001 Dec 7;(23):2414-5. doi: 10.1039/b106472j. Chem Commun (Camb). 2001. PMID: 12239992
Octanuclearity and tetradecanuclearity in manganese chemistry: an octanuclear manganese(II)/(III) complex featuring the novel [Mn8(mu4-O)2(mu3-OH)2]14+ core and [Mn10(II)Mn4(III)O4(O2CMe)20[(2-py)2C(OH)O]4] (2-py = 2-pyridyl).
Milios CJ, Kefalloniti E, Raptopoulou CP, Terzis A, Vicente R, Lalioti N, Escuer A, Perlepes SP. Milios CJ, et al. Among authors: perlepes sp. Chem Commun (Camb). 2003 Apr 7;(7):819-21. doi: 10.1039/b300986f. Chem Commun (Camb). 2003. PMID: 12739628
Hexanuclear manganese(III) single-molecule magnets.
Milios CJ, Raptopoulou CP, Terzis A, Lloret F, Vicente R, Perlepes SP, Escuer A. Milios CJ, et al. Among authors: perlepes sp. Angew Chem Int Ed Engl. 2004 Jan;43(2):210-2. doi: 10.1002/anie.200351079. Angew Chem Int Ed Engl. 2004. PMID: 14695611 No abstract available.
A nonanuclear iron(II) single-molecule magnet.
Boudalis AK, Donnadieu B, Nastopoulos V, Clemente-Juan JM, Mari A, Sanakis Y, Tuchagues JP, Perlepes SP. Boudalis AK, et al. Among authors: perlepes sp. Angew Chem Int Ed Engl. 2004 Apr 19;43(17):2266-70. doi: 10.1002/anie.200353147. Angew Chem Int Ed Engl. 2004. PMID: 15108140 No abstract available.
Di-2-pyridyl ketone oxime [(py)2CNOH] in manganese carboxylate chemistry: mononuclear, dinuclear and tetranuclear complexes, and partial transformation of (py)2CNOH to the gem-diolate(2-) derivative of di-2-pyridyl ketone leading to the formation of NO3-.
Milios CJ, Kyritsis P, Raptopoulou CP, Terzis A, Vicente R, Escuer A, Perlepes SP. Milios CJ, et al. Among authors: perlepes sp. Dalton Trans. 2005 Feb 7;(3):501-11. doi: 10.1039/b412355g. Epub 2005 Jan 5. Dalton Trans. 2005. PMID: 15672194
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