Intra- and intermolecular N-H...F-C hydrogen-bonding interactions in amine adducts of tris(pentafluorophenyl)borane and -alane.
Mountford AJ, Lancaster SJ, Coles SJ, Horton PN, Hughes DL, Hursthouse MB, Light ME.
Mountford AJ, et al. Among authors: light me.
Inorg Chem. 2005 Aug 8;44(16):5921-33. doi: 10.1021/ic050663n.
Inorg Chem. 2005.
PMID: 16060648
The reaction between B(C(6)F(5))(3) and NH(3)(g) in light petroleum yielded the solvated adduct H(3)N.B(C(6)F(5))(3).NH(3). Treatment with a second equivalent of B(C(6)F(5))(3) afforded H(3)N.B(C(6)F(5))(3). ...Related compounds of the form R'R' 'N(H).M(C(6)F(5))(3) were s …
The reaction between B(C(6)F(5))(3) and NH(3)(g) in light petroleum yielded the solvated adduct H(3)N.B(C(6)F(5))(3).NH(3). Treatment …