Reaction products with internal energy beyond the kinematic limit result from trajectories far from the minimum energy path: an example from H + HBr --> H2 + Br.
J Am Chem Soc. 2005 Nov 30;127(47):16368-9. doi: 10.1021/ja055440a.
J Am Chem Soc. 2005.
PMID: 16305203