Byrne PA - Search Results

1

A convenient and mild chromatography-free method for the purification of the products of Wittig and Appel reactions.

Byrne PA, Rajendran KV, Muldoon J, Gilheany DG. Byrne PA, et al. Org Biomol Chem. 2012 May 7;10(17):3531-7. doi: 10.1039/c2ob07074j. Epub 2012 Mar 22. Org Biomol Chem. 2012. PMID: 22437367

2

Unequivocal experimental evidence for a unified lithium salt-free Wittig reaction mechanism for all phosphonium Ylide types: reactions with β-heteroatom-substituted aldehydes are consistently selective for cis-oxaphosphetane-derived products.

Byrne PA, Gilheany DG. Byrne PA, et al. J Am Chem Soc. 2012 Jun 6;134(22):9225-39. doi: 10.1021/ja300943z. Epub 2012 May 25. J Am Chem Soc. 2012. PMID: 22559814

3

The modern interpretation of the Wittig reaction mechanism.

Byrne PA, Gilheany DG. Byrne PA, et al. Chem Soc Rev. 2013 Aug 21;42(16):6670-96. doi: 10.1039/c3cs60105f. Chem Soc Rev. 2013. PMID: 23673458 Review.

4

First ever observation of the intermediate of phosphonium salt and ylide hydrolysis: P-hydroxytetraorganophosphorane.

Byrne PA, Ortin Y, Gilheany DG. Byrne PA, et al. Chem Commun (Camb). 2015 Jan 21;51(6):1147-50. doi: 10.1039/c4cc08644a. Chem Commun (Camb). 2015. PMID: 25467386

5

The Mechanism of Phosphonium Ylide Alcoholysis and Hydrolysis: Concerted Addition of the O-H Bond Across the P=C Bond.

Byrne PA, Gilheany DG. Byrne PA, et al. Chemistry. 2016 Jun 27;22(27):9140-54. doi: 10.1002/chem.201600530. Epub 2016 Jun 6. Chemistry. 2016. PMID: 27272656

6

Nucleophilicities and Nucleofugalities of Thio- and Selenoethers.

Maji B, Duan XH, Jüstel PM, Byrne PA, Ofial AR, Mayr H. Maji B, et al. Among authors: byrne pa. Chemistry. 2021 Aug 5;27(44):11367-11376. doi: 10.1002/chem.202100977. Epub 2021 Jun 30. Chemistry. 2021. PMID: 34002899 Free PMC article.

7

Ambident Reactivity of Acetyl- and Formyl-Stabilized Phosphonium Ylides.

Byrne PA, Karaghiosoff K, Mayr H. Byrne PA, et al. J Am Chem Soc. 2016 Sep 7;138(35):11272-81. doi: 10.1021/jacs.6b06264. Epub 2016 Aug 24. J Am Chem Soc. 2016. PMID: 27499510

8

Competition between N and O: use of diazine N-oxides as a test case for the Marcus theory rationale for ambident reactivity.

Sheehy KJ, Bateman LM, Flosbach NT, Breugst M, Byrne PA. Sheehy KJ, et al. Among authors: byrne pa. Chem Sci. 2020 Jul 23;11(35):9630-9647. doi: 10.1039/d0sc02834g. Chem Sci. 2020. PMID: 34094230 Free PMC article.

9

Why Are Vinyl Cations Sluggish Electrophiles?

Byrne PA, Kobayashi S, Würthwein EU, Ammer J, Mayr H. Byrne PA, et al. J Am Chem Soc. 2017 Feb 1;139(4):1499-1511. doi: 10.1021/jacs.6b10889. Epub 2017 Jan 20. J Am Chem Soc. 2017. PMID: 28040896

10

The study of in vivo quantification of aluminum (Al) in human bone with a compact DD generator-based neutron activation analysis (NAA) system.

Byrne P, Mostafaei F, Liu Y, Blake SP, Koltick D, Nie LH. Byrne P, et al. Physiol Meas. 2016 May;37(5):649-60. doi: 10.1088/0967-3334/37/5/649. Epub 2016 Apr 19. Physiol Meas. 2016. PMID: 27093035 Free PMC article.

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