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An inverted and more oxidizing isomer of [Fe(IV)(O)(tmc)(NCCH3)]2+.
Ray K, England J, Fiedler AT, Martinho M, Münck E, Que L Jr. Ray K, et al. Among authors: fiedler at. Angew Chem Int Ed Engl. 2008;47(42):8068-71. doi: 10.1002/anie.200802219. Angew Chem Int Ed Engl. 2008. PMID: 18798182 Free PMC article. No abstract available.
Mössbauer and DFT study of the ferromagnetically coupled diiron(IV) precursor to a complex with an Fe(IV)(2)O(2) diamond core.
Martinho M, Xue G, Fiedler AT, Que L Jr, Bominaar EL, Münck E. Martinho M, et al. Among authors: fiedler at. J Am Chem Soc. 2009 Apr 29;131(16):5823-30. doi: 10.1021/ja8098917. J Am Chem Soc. 2009. PMID: 19338307 Free PMC article.
The ferromagnetic behavior of 2 seems puzzling given that the Fe-(mu-O)-Fe angle is large but can be explained by noting that the orbital structures of Fe(O) and Fe(OH) are such that the unpaired electrons at the two sites delocalize into orthogonal orbitals at the …
The ferromagnetic behavior of 2 seems puzzling given that the Fe-(mu-O)-Fe angle is large but can be explained by noting that the orbital st …
44 results