Electronic structure and reactivity of low-spin Fe(III)-hydroperoxo complexes: comparison to activated bleomycin.
Lehnert N, Neese F, Ho RY, Que L Jr, Solomon EI.
Lehnert N, et al. Among authors: neese f.
J Am Chem Soc. 2002 Sep 11;124(36):10810-22. doi: 10.1021/ja012621d.
J Am Chem Soc. 2002.
PMID: 12207537
In contrast, ABLM has a somewhat different electronic structure where no pi donor bond between the hydroperoxo ligand and iron(III) is present [Neese, F.; Zaleski, J. M.; Loeb-Zaleski, K.; Solomon, E. I. J. Am. Chem. Soc. 2000, 122, 11703]. ...
In contrast, ABLM has a somewhat different electronic structure where no pi donor bond between the hydroperoxo ligand and iron(III) is prese …