Reversible or Irreversible Catalysis of H+/H2 Conversion by FeFe Hydrogenases.
Fasano A, Land H, Fourmond V, Berggren G, Léger C.
Fasano A, et al. Among authors: land h.
J Am Chem Soc. 2021 Dec 8;143(48):20320-20325. doi: 10.1021/jacs.1c09554. Epub 2021 Nov 23.
J Am Chem Soc. 2021.
PMID: 34813699
To understand the determinants of catalytic (ir)reversibility, we examined the steady-state, direct electron transfer voltammetry of a particular FeFe hydrogenase, from Thermoanaerobacter mathranii, which is very unusual in that it irreversibly catalyzes H(2) oxidation and …
To understand the determinants of catalytic (ir)reversibility, we examined the steady-state, direct electron transfer voltammetry of a parti …