Characterization of the dynamics in the protonic conductor CsH₂PO₄ by ¹⁷O solid-state NMR spectroscopy and first-principles calculations: correlating phosphate and protonic motion.
Kim G, Griffin JM, Blanc F, Haile SM, Grey CP.
Kim G, et al.
J Am Chem Soc. 2015 Mar 25;137(11):3867-76. doi: 10.1021/jacs.5b00280. Epub 2015 Mar 16.
J Am Chem Soc. 2015.
PMID: 25732257
Free PMC article.
The activation energy of this process is slightly lower than that obtained from the (1)H exchange process (0.70 0.07 eV) (Kim, G.; Blanc, F.; Hu, Y.-Y.; Grey, C. P. J. Phys. Chem. C 2013, 117, 6504-6515) associated with the translational motion of the protons. ...
The activation energy of this process is slightly lower than that obtained from the (1)H exchange process (0.70 0.07 eV) (Kim, G …