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Reactions of diborenes with terminal alkynes: mechanisms of ligand-controlled anti-selective hydroalkynylation, cycloaddition and C[triple bond, length as m-dash]C triple bond scission.
Englert L, Schmidt U, Dömling M, Passargus M, Stennett TE, Hermann A, Arrowsmith M, Härterich M, Müssig J, Phillipps A, Prieschl D, Rempel A, Rohm F, Radacki K, Schorr F, Thiess T, Jiménez-Halla JOC, Braunschweig H. Englert L, et al. Among authors: harterich m. Chem Sci. 2021 Jun 21;12(27):9506-9515. doi: 10.1039/d1sc02081a. eCollection 2021 Jul 14. Chem Sci. 2021. PMID: 34349926 Free PMC article.
Cyclo-Dipnictadialanes.
Nees S, Fantuzzi F, Wellnitz T, Fischer M, Siewert JE, Goettel JT, Hofmann A, Härterich M, Braunschweig H, Hering-Junghans C. Nees S, et al. Among authors: harterich m. Angew Chem Int Ed Engl. 2021 Nov 2;60(45):24318-24325. doi: 10.1002/anie.202111121. Epub 2021 Oct 5. Angew Chem Int Ed Engl. 2021. PMID: 34478231 Free PMC article.
An Unsymmetrical, Cyclic Diborene Based on a Chelating CAAC Ligand and its Small-Molecule Activation and Rearrangement Chemistry.
Lu W, Jayaraman A, Fantuzzi F, Dewhurst RD, Härterich M, Dietz M, Hagspiel S, Krummenacher I, Hammond K, Cui J, Braunschweig H. Lu W, et al. Among authors: harterich m. Angew Chem Int Ed Engl. 2022 Jan 17;61(3):e202113947. doi: 10.1002/anie.202113947. Epub 2021 Dec 3. Angew Chem Int Ed Engl. 2022. PMID: 34750945 Free PMC article.
Evidence for Borylene Carbonyl (LHB═C═O) and Base-Stabilized (LHB═O) and Base-Free Oxoborane (RB≡O) Intermediates in the Reactions of Diborenes with CO2.
Stoy A, Härterich M, Dewhurst RD, Jiménez-Halla JOC, Endres P, Eyßelein M, Kupfer T, Deissenberger A, Thiess T, Braunschweig H. Stoy A, et al. Among authors: harterich m. J Am Chem Soc. 2022 Mar 2;144(8):3376-3380. doi: 10.1021/jacs.2c00479. Epub 2022 Feb 18. J Am Chem Soc. 2022. PMID: 35179031
19 results