Nikitin K - Search Results

1

Unexpected rapid P-stereomutation of phosphine oxides catalysed by chlorophosphonium salts.

Al-Sulaimi S, Rajendran K, Nikitin K, Gilheany DG. Al-Sulaimi S, et al. Among authors: nikitin k. Chem Commun (Camb). 2023 Sep 28;59(78):11696-11699. doi: 10.1039/d3cc03719c. Chem Commun (Camb). 2023. PMID: 37700722

2

Long sought synthesis of quaternary phosphonium salts from phosphine oxides: inverse reactivity approach.

Vetter AC , Nikitin K , Gilheany DG . Vetter AC , et al. Among authors: nikitin k. Chem Commun (Camb). 2018 Jun 5;54(46):5843-5846. doi: 10.1039/c8cc02173b. Chem Commun (Camb). 2018. PMID: 29714382

3

Direct evidence of a multicentre halogen bond: unexpected contraction of the P-XXX-P fragment in triphenylphosphine dihalides.

Nikitin K, Müller-Bunz H, Gilheany D. Nikitin K, et al. Chem Commun (Camb). 2013 Feb 18;49(14):1434-6. doi: 10.1039/c2cc38363b. Chem Commun (Camb). 2013. PMID: 23322232

4

Turning regioselectivity into stereoselectivity: efficient dual resolution of P-stereogenic phosphine oxides through bifurcation of the reaction pathway of a common intermediate.

Nikitin K, Rajendran KV, Müller-Bunz H, Gilheany DG. Nikitin K, et al. Angew Chem Int Ed Engl. 2014 Feb 10;53(7):1906-9. doi: 10.1002/anie.201309556. Epub 2014 Jan 29. Angew Chem Int Ed Engl. 2014. PMID: 24474623

5

Degenerate nucleophilic substitution in phosphonium salts.

Jennings EV, Nikitin K, Ortin Y, Gilheany DG. Jennings EV, et al. Among authors: nikitin k. J Am Chem Soc. 2014 Nov 19;136(46):16217-26. doi: 10.1021/ja507433g. Epub 2014 Nov 11. J Am Chem Soc. 2014. PMID: 25384344

6

Hammond Postulate Mirroring Enables Enantiomeric Enrichment of Phosphorus Compounds via Two Thermodynamically Interconnected Sequential Stereoselective Processes.

Rajendran KV, Nikitin KV, Gilheany DG. Rajendran KV, et al. J Am Chem Soc. 2015 Jul 29;137(29):9375-81. doi: 10.1021/jacs.5b04415. Epub 2015 Jul 17. J Am Chem Soc. 2015. PMID: 26186272

7

Two Independent Orthogonal Stereomutations at a Single Asymmetric Center: A Narcissistic Couple.

Gillick-Healy MW, Jennings EV, Müller-Bunz H, Ortin Y, Nikitin K, Gilheany DG. Gillick-Healy MW, et al. Among authors: nikitin k. Chemistry. 2017 Feb 16;23(10):2332-2339. doi: 10.1002/chem.201604080. Epub 2016 Dec 21. Chemistry. 2017. PMID: 27779793

8

Mysterious Decomposition of Alkoxyphosphonium Chlorides: Postulated Involvement of the HCl₂ Anion and Its Capture in the Solid State.

Nikitin K, Müller-Bunz H, Muldoon J, Gilheany DG. Nikitin K, et al. Chemistry. 2017 Apr 6;23(20):4794-4802. doi: 10.1002/chem.201604898. Epub 2017 Feb 6. Chemistry. 2017. PMID: 28164404

9

Dynamic Cross-Exchange in Halophosphonium Species: Direct Observation of Stereochemical Inversion in the Course of an S_N 2 Process.

Nikitin K, Jennings EV, Al Sulaimi S, Ortin Y, Gilheany DG. Nikitin K, et al. Angew Chem Int Ed Engl. 2018 Feb 5;57(6):1480-1484. doi: 10.1002/anie.201708649. Epub 2017 Dec 6. Angew Chem Int Ed Engl. 2018. PMID: 29149539

10

Wittig Olefination Using Phosphonium Ion-Pair Reagents Incorporating an Endogenous Base.

Vetter AC, Gilheany DG, Nikitin K. Vetter AC, et al. Among authors: nikitin k. Org Lett. 2021 Feb 19;23(4):1457-1462. doi: 10.1021/acs.orglett.1c00133. Epub 2021 Feb 2. Org Lett. 2021. PMID: 33529039

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