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Organic chemistry. Strain-release amination.
Gianatassio R, Lopchuk JM, Wang J, Pan CM, Malins LR, Prieto L, Brandt TA, Collins MR, Gallego GM, Sach NW, Spangler JE, Zhu H, Zhu J, Baran PS. Gianatassio R, et al. Science. 2016 Jan 15;351(6270):241-6. doi: 10.1126/science.aad6252. Science. 2016. PMID: 26816372 Free PMC article.
Simple sulfinate synthesis enables C-H trifluoromethylcyclopropanation.
Gianatassio R, Kawamura S, Eprile CL, Foo K, Ge J, Burns AC, Collins MR, Baran PS. Gianatassio R, et al. Angew Chem Int Ed Engl. 2014 Sep 8;53(37):9851-5. doi: 10.1002/anie.201406622. Epub 2014 Aug 3. Angew Chem Int Ed Engl. 2014. PMID: 25088979 Free PMC article.
A P(V) platform for oligonucleotide synthesis.
Huang Y, Knouse KW, Qiu S, Hao W, Padial NM, Vantourout JC, Zheng B, Mercer SE, Lopez-Ogalla J, Narayan R, Olson RE, Blackmond DG, Eastgate MD, Schmidt MA, McDonald IM, Baran PS. Huang Y, et al. Science. 2021 Sep 10;373(6560):1265-1270. doi: 10.1126/science.abi9727. Epub 2021 Sep 9. Science. 2021. PMID: 34516793 Free PMC article.
Mechanistic Insights into Two-Phase Radical C-H Arylations.
Baxter RD, Liang Y, Hong X, Brown TA, Zare RN, Houk KN, Baran PS, Blackmond DG. Baxter RD, et al. ACS Cent Sci. 2015 Nov 25;1(8):456-462. doi: 10.1021/acscentsci.5b00332. Epub 2015 Nov 2. ACS Cent Sci. 2015. PMID: 26640819 Free PMC article.
Bioconjugation by native chemical tagging of C-H bonds.
Zhou Q, Gui J, Pan CM, Albone E, Cheng X, Suh EM, Grasso L, Ishihara Y, Baran PS. Zhou Q, et al. J Am Chem Soc. 2013 Sep 4;135(35):12994-7. doi: 10.1021/ja407739y. Epub 2013 Aug 22. J Am Chem Soc. 2013. PMID: 23957305 Free PMC article.
13 results