Multiple-quantum relaxation in the magic-angle-spinning NMR of 13C spin pairs

Solid State Nucl Magn Reson. 1999 Jun;14(1):43-58. doi: 10.1016/s0926-2040(99)00008-9.

Abstract

We determine the decay rate constants of zero-, double- and single-quantum coherence for 13C spin pairs in magic-angle-spinning solid-state NMR. The double-quantum coherence is excited by a C7 pulse sequence and converted into zero-quantum coherence by a frequency-selective pair of pi/2 pulses. The zero-quantum coherence is reconverted into observable magnetization by a second pair of pi/2 pulses followed by a second C7 sequence. In a magnetically dilute system where the 13C-13C distance is 0.296 nm, the relaxation rate constants are consistent with a model of uncorrelated random fields at the two labeled 13C sites. In a fully-labelled system with a short 13C-13C distance of 0.153 nm, the measured rate constants are inconsistent with the uncorrelated random field model.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Carbon Isotopes*
  • Glycine / chemistry*
  • Magnetic Resonance Spectroscopy / methods*
  • Mathematics
  • Molecular Structure
  • Quantum Theory
  • Retinaldehyde / chemistry*
  • Spectrum Analysis
  • Spin Trapping

Substances

  • Carbon Isotopes
  • Retinaldehyde
  • Glycine