Determination of deltamethrin in cattle dipping baths by high-performance liquid chromatography

J Agric Food Chem. 1999 Jan;47(1):174-6. doi: 10.1021/jf980171b.

Abstract

Deltamethrin (S)-alpha-cyano-3-phenoxybenzyl) (1R,3R)-3-(2, 2-dibromovinyl)-2,2-dimethylcyclopropane-1-carboxylate is classified as a pyrethroid pesticide that is largely used as an acaricide and scabicide. For bovines, especially, the treatment is done with the aid of dipping baths of the pyrethroid solution. Analytical control of the concentration of deltamethrin in these baths must be done periodically in order to guarantee treatment efficacy. In the proposed procedure, the sample is prepared by centrifugation followed by filtration and measurement by high-performance liquid chromatography (HPLC) with spectrophotometric detection at 275 nm. Separation is done in a Nucleosil C-18 column with acetonitrile-water as the mobile phase. A calibration curve was constructed with external standards, and a detection limit of 0.2 mg L(-)(1) was obtained. In the samples analyzed, only ca. 20% of the total deltamethrin content was found in the solution. The results obtained demonstrate the potential of the described procedure for the determination of deltamethrin in animal baths.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animal Husbandry
  • Animals
  • Cattle
  • Cattle Diseases / prevention & control
  • Chromatography, High Pressure Liquid / methods*
  • Insecticides / analysis*
  • Nitriles
  • Pyrethrins / analysis*
  • Reproducibility of Results
  • Spectrophotometry, Ultraviolet

Substances

  • Insecticides
  • Nitriles
  • Pyrethrins
  • decamethrin