A Dicubane-Like Tetrameric Nickel(II) Azido Complex

Angew Chem Int Ed Engl. 2000 Jan;39(2):344-347. doi: 10.1002/(sici)1521-3773(20000117)39:2<344::aid-anie344>3.0.co;2-1.

Abstract

A combination of azido and dipyridylketone (dpk) ligands led to the isolation of the tetranuclear Ni(II) complex 1 (dpkOH and dpkOCH(3) result from solvolysis of dpk). The complex exhibits ferromagnetic behavior, and its structure can be described as a dicubane unit with two missing vertices (see picture).