Mass spectrometric study of tricarbonyl (eta(6)-phenyl methanols) of chromium(0)

G A Arroyo; R Miranda; J G García; F Delgado; L Cessa; F J Pérez; L Velasco

doi:10.1002/(SICI)1097-0231(20000331)14:6<444::AID-RCM888>3.0.CO;2-G

Mass spectrometric study of tricarbonyl (eta(6)-phenyl methanols) of chromium(0)

Rapid Commun Mass Spectrom. 2000;14(6):444-9. doi: 10.1002/(SICI)1097-0231(20000331)14:6<444::AID-RCM888>3.0.CO;2-G.

Authors

G A Arroyo¹, R Miranda, J G García, F Delgado, L Cessa, F J Pérez, L Velasco

Affiliation

¹ Facultad de Estudios Superiores Cuautitlán-Universidad Nacional Autónoma de México, Campo 1, Cuautitlán Izcalil, Estado de México, C.P. 054740, USA.

PMID: 10717653
DOI: 10.1002/(SICI)1097-0231(20000331)14:6<444::AID-RCM888>3.0.CO;2-G

Abstract

A mass spectrometric study of several tricarbonyl (eta(6)-phenyl methanols) of chromium(0) was performed. Electron ionization (EI), chemical ionization (CI) and fast atom bombardment (FAB) mass spectra were acquired for each molecule, and compared in order to establish a general fragmentation pattern. The suggested pathways were investigated and confirmed by means of constant b/e linked scans and high resolution data. In addition a Hammett-McLafferty correlation for some peaks derived from the molecular ions was accomplished.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Chromium / chemistry*
Magnetic Resonance Spectroscopy
Mass Spectrometry
Organometallic Compounds / chemistry*
Spectrometry, Mass, Fast Atom Bombardment*

Substances

Organometallic Compounds
Chromium