Purification and biochemical characterization of a novel thermostable lipase from Aspergillus niger

Lipids. 2000 May;35(5):495-502. doi: 10.1007/s11745-000-549-3.

Abstract

An extracellular 1,3-specific lipase with molecular weight of 35.5 kDa and an isoelectric point of 4.4 from Aspergillus niger has been purified 50-fold by pH precipitation followed by a series of chromatographic steps with an overall yield of 10%. The enzyme was homogeneous as judged by denaturing polyacrylamide gel electrophoresis and size-exclusion fast-performance liquid chromatography. It contained 2.8% sugar which was completely removed by endoglycosidase F treatment, and the deglycosylated enzyme retained full activity. The native lipase showed optimal activity between temperatures 35 and 55 degrees C and pH 5.0 and 6.0. The amino acid composition and the N-terminal sequence were found to be different from lipases previously purified from A. niger. The enzyme was resistant to trypsin, chymotrypsin, endoprotease Glu-C, thrombin, and papain under native conditions but was susceptible to cleavage by the same proteases when heat-denatured.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aspergillus niger / enzymology*
  • Chromatography
  • Chromatography, Liquid
  • Chromatography, Thin Layer
  • Chymotrypsin / pharmacology
  • Electrophoresis, Polyacrylamide Gel
  • Hydrogen-Ion Concentration
  • Isoelectric Focusing
  • Lipase / chemistry*
  • Lipase / isolation & purification*
  • Mannosyl-Glycoprotein Endo-beta-N-Acetylglucosaminidase / pharmacology
  • Papain / pharmacology
  • Temperature
  • Thrombin / pharmacology
  • Time Factors
  • Trypsin / pharmacology

Substances

  • Lipase
  • Mannosyl-Glycoprotein Endo-beta-N-Acetylglucosaminidase
  • Chymotrypsin
  • Trypsin
  • Thrombin
  • Papain