Degradation of bisphenol A by the lignin-degrading enzyme, manganese peroxidase, produced by the white-rot basidiomycete, Pleurotus ostreatus

Biosci Biotechnol Biochem. 2000 Sep;64(9):1958-62. doi: 10.1271/bbb.64.1958.

Abstract

Degradation of 2,2-Bis(4-hydroxyphenyl)propane (bisphenol A, BPA), an endocrine-disturbing chemical, by the growing mycelia of the white-rot basidiomycete, Pleurotus ostreatus, was examined. About 80% of BPA initially present decreased in 12 days of culture with this fungus. By in vitro experiments using the lignin-degrading enzyme manganese peroxidase (MnP), BPA was metabolized to phenol, 4-isopropenylphenol, 4-isopropylphenol, and hexestrol. The degradation products of BPA were assumed to be formed by the one-electron oxidation of the substrate.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Air Pollutants, Occupational / pharmacokinetics
  • Benzhydryl Compounds
  • Biodegradation, Environmental
  • Lignin / metabolism*
  • Peroxidases / metabolism*
  • Phenols / chemistry
  • Phenols / pharmacokinetics*
  • Pleurotus / enzymology*

Substances

  • Air Pollutants, Occupational
  • Benzhydryl Compounds
  • Phenols
  • Lignin
  • Peroxidases
  • manganese peroxidase
  • bisphenol A