High-performance liquid chromatographic analysis of the tyrphostin AG1478, a specific inhibitor of the epidermal growth factor receptor tyrosine kinase, in mouse plasma

J Chromatogr B Biomed Sci Appl. 2001 Apr 15;754(1):193-9. doi: 10.1016/s0378-4347(00)00606-x.

Abstract

The tyrphostin 4-(3-chloroanilino)-6,7-dimethoxyquinazoline (AG1478) is undergoing evaluation as a potential new anticancer agent. We have developed a specific and sensitive reversed-phase HPLC assay for AG1478 in mouse plasma. The method involves a rapid and simple extraction process followed by separation on a Symmetry C8 stationary phase with a gradient of acetonitrile in ammonium acetate buffer. A linear response was achieved over the concentration range of 0.2-100 microM using multilevel calibration with internal standard method of calculation. Inter- and intra-assay accuracy and precision were better than +/-10%. The limit of quantitation was 0.2 microM. We have used this method to study the preclinical pharmacokinetics of this new agent in mice.

MeSH terms

  • Animals
  • Chromatography, High Pressure Liquid / methods*
  • Enzyme Inhibitors / blood
  • Enzyme Stability
  • ErbB Receptors / antagonists & inhibitors*
  • Freezing
  • Mice
  • Quinazolines
  • Reference Standards
  • Sensitivity and Specificity
  • Tyrphostins / blood*
  • Tyrphostins / pharmacokinetics

Substances

  • Enzyme Inhibitors
  • Quinazolines
  • Tyrphostins
  • RTKI cpd
  • ErbB Receptors