Analysis of terpenelactones in Ginkgo biloba by high performance liquid chromatography and evaporative light scattering detection

Chem Pharm Bull (Tokyo). 2001 Sep;49(9):1170-3. doi: 10.1248/cpb.49.1170.

Abstract

A reversed phase HPLC method permitting the determination of 5 terpenelactones in Ginkgo biloba, without the need of any sample preparation is presented in this paper. The compounds were successfully separated within 25 min by using a C-12 column, an evaporative light scattering (ELS) detector and a mobile phase comprising of ammonium acetate buffer, methanol and isobutanol. All terpenelactones were detectable at concentrations as low as 20.3 microg/ml. The analysis of G. biloba market products showed remarkable variations in the lactone content, and more than 2 fold differences in the suggested daily doses of the total lactones, from 8.84 mg to 18.28 mg, respectively.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Calibration
  • Chromatography, High Pressure Liquid
  • Ginkgo biloba / chemistry*
  • Lactones / analysis*
  • Light
  • Mass Spectrometry
  • Molecular Conformation
  • Scattering, Radiation
  • Spectrophotometry, Ultraviolet
  • Terpenes / analysis*

Substances

  • Lactones
  • Terpenes