Coordination chemistry umpolung: a gallane ligand on a phosphine lewis acceptor

Neil Burford; Paul J Ragogna; Katherine N Robertson; T Stanley Cameron; Ned J Hardman; Philip P Power

doi:10.1021/ja012081k

Coordination chemistry umpolung: a gallane ligand on a phosphine lewis acceptor

J Am Chem Soc. 2002 Jan 23;124(3):382-3. doi: 10.1021/ja012081k.

Authors

Neil Burford¹, Paul J Ragogna, Katherine N Robertson, T Stanley Cameron, Ned J Hardman, Philip P Power

Affiliation

¹ Department of Chemistry, Dalhousie University, Halifax, Nova Scotia, Canada.

PMID: 11792201
DOI: 10.1021/ja012081k

Abstract

Pentaphenylphosphinophosphonium trifluoromethanesulfonate reacts with amino-iminogall(I)ane to effect quantitative substitution of Ph3P and formation of the first complex of a gallium Lewis base on a phosphine Lewis acid.