The enantiomers of carbocyclic 5'-norguanosine: activity towards Epstein-Barr virus

Bioorg Med Chem. 2002 Apr;10(4):883-6. doi: 10.1016/s0968-0896(01)00344-3.

Abstract

(-)-5'-noraristeromycin (1) has shown antiviral activity towards, particularly cytomegalovirus, vaccinia virus and measles while its (+)-enantiomer (2) is effective towards hepatitis B virus. To determine if the antiviral characteristics of 1 and 2 extended to the guanine analogues (3 and 4), these enantiomers were prepared and evaluated against herpes simplex virus type 1 (HSV-1) and type 2 (HSV-2), cytomegalovirus (CMV), varicella zoster virus (VZV), Epstein-Barr virus (EBV), human herpes virus type 6 (HHV-6), human herpes virus type 8 (HHV-8), vaccinia virus (VV), cowpox virus (CV), vesicular stomatitis virus (VSV), respiratory syncytial virus (RSV), hepatitis B virus (HBV), and human immunodeficiency virus type 1 (HIV-1) and type 2 (HIV-2). The only activity found for 3 was for Epstein-Barr virus in VCA Elisa (EC50 0.78 microg/mL), immunofluorescence assay for VCA or gp 350/250 (1.8-4.0 microg/mL) and DNA hybridization (EC50 0.82 microg/mL) assays with no accompanying toxicity seen in the host Daudi cells. No activity was noted for 4.

Publication types

  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Antiviral Agents / chemical synthesis*
  • Antiviral Agents / pharmacology
  • Antiviral Agents / toxicity
  • Guanosine / analogs & derivatives
  • Guanosine / chemical synthesis
  • Guanosine / pharmacology*
  • Guanosine / toxicity
  • Herpesvirus 4, Human / drug effects*
  • Humans
  • Microbial Sensitivity Tests
  • Stereoisomerism
  • Structure-Activity Relationship
  • Tumor Cells, Cultured
  • Viruses / drug effects

Substances

  • Antiviral Agents
  • carbocyclic 5'-norguanosine
  • Guanosine