Rational design of alpha-helical antifreeze peptides

J Pept Res. 2002 Jan;59(1):1-8. doi: 10.1046/j.1397-002x.2001.00001.x.

Abstract

The alanine-rich alpha-helical antifreeze protein from the winter flounder Pseudopleuronectes americanus adsorbs to specific planes of ice guided by an ice lattice match to threonine residues regularly spaced 16.6 A apart. We report here that by redesigning the winter flounder antifreeze peptide to incorporate a 27.1-A spacing between putative 'ice-binding' threonines, the deduced binding alignment of the helical molecule on the ice lattice is changed from the Miller indices directional vector [1102 ] to [2203 ]. Subsequent ice-binding characteristics are altered, including changes in adsorption specificity, decreases in thermal hysteresis activity and the formation of rotated hexagonal bipyramid ice crystal morphology.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Acid Sequence
  • Antifreeze Proteins / chemistry*
  • Antifreeze Proteins / metabolism
  • Antifreeze Proteins / pharmacology
  • Crystallization
  • Drug Design
  • Ice
  • Models, Molecular
  • Molecular Sequence Data
  • Protein Structure, Secondary

Substances

  • Antifreeze Proteins
  • Ice