1,3-Bridged p-methyloctahomotetraoxacalix[4]arene-bis-crown-3

Acta Crystallogr C. 2002 Jun;58(Pt 6):o345-6. doi: 10.1107/s0108270102006868. Epub 2002 May 21.

Abstract

The title compound, 13,21,35,43-tetramethyl-3,6,9,17,25,28,31,39,46,49-decaoxaheptacyclo[21.21.3.3(11,33).0(2,41).0(10,15).0(19,24).0(32,37)]pentaconta-1,10,12,14,19,21,23,32,34,36,41,43-dodecaene, C(44)H(52)O(10), differs from previously reported 1,3-bridged calix[4]arene[bond]bis-crown compounds in having an enlarged calixarene ring and shorter polyoxyethylene bridges. The cavity is partly filled by the bridges.