Peracetylated sugar derivatives show high solubility in liquid and supercritical carbon dioxide

Vijay K Potluri; Jianhang Xu; Robert Enick; Eric Beckman; Andrew D Hamilton

doi:10.1021/ol026007y

Peracetylated sugar derivatives show high solubility in liquid and supercritical carbon dioxide

Org Lett. 2002 Jul 11;4(14):2333-5. doi: 10.1021/ol026007y.

Authors

Vijay K Potluri¹, Jianhang Xu, Robert Enick, Eric Beckman, Andrew D Hamilton

Affiliation

¹ Department of Chemistry, Yale University, PO Box 208107, New Haven, Connecticut 06520-8107, USA.

PMID: 12098240
DOI: 10.1021/ol026007y

Abstract

[structure: see text] Acetylated sugars derivatives exhibit high solubility in liquid and supercritical carbon dioxide (scCO(2)). Peracetylated sorbitol and beta-D-galactose are soluble under mild conditions in scCO(2), high pressures are required to dissolve peracetylated beta-cyclodextrin, and peracetoxyalkyl chains impart CO(2)-solubility to amides.

Publication types

Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

Acetylation
Carbohydrate Sequence
Carbohydrates / chemical synthesis
Carbohydrates / chemistry*
Carbon Dioxide / chemistry*
Cyclodextrins / chemistry
Molecular Sequence Data
Solubility
Solvents
beta-Cyclodextrins*

Substances

Carbohydrates
Cyclodextrins
Solvents
beta-Cyclodextrins
Carbon Dioxide
betadex