Abstract
Reaction of meso-(2-formylvinyl)octaethylporphyrin with (CH3)3SiCN-Cu(OTf)2 produced unexpected 10(3)-trimethylsiloxyl and 10(3)-hydroxyl fused propenochlorins which, in H2SO4, underwent subsequent migration of the 8-ethyl group to the 10(3)-position of the exocyclic benzene ring to form a novel benzochlorin.
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, P.H.S.
MeSH terms
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Crystallography, X-Ray
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Deuteroporphyrins / chemical synthesis
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Deuteroporphyrins / chemistry
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Magnetic Resonance Spectroscopy
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Photochemotherapy
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Photosensitizing Agents / chemical synthesis*
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Photosensitizing Agents / chemistry
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Porphyrins / chemical synthesis*
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Porphyrins / chemistry
Substances
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Deuteroporphyrins
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Photosensitizing Agents
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Porphyrins