Abstract
Singlet oxygen reacts with Ir(I) and Rh(I) thiolato complexes to form the corresponding Ir(III) and Rh(III) peroxo thiolato complexes which do not undergo intramolecular oxidation of the thiolate moiety.
Publication types
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, P.H.S.
MeSH terms
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Electrons
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Iridium / chemistry*
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Ligands
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Organometallic Compounds / chemistry
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Oxygen / chemistry*
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Rhodium / chemistry*
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Sulfhydryl Compounds / chemistry*
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Sulfur / chemistry
Substances
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Ligands
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Organometallic Compounds
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Sulfhydryl Compounds
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Iridium
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Sulfur
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Rhodium
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Oxygen