Abstract
The photophysics of fac-[(dppz-12-NO2)Re(CO)3(4-Me2Npy)]+ in CH3CN have been investigated using picosecond time-resolved IR (ps-TRIR) spectroscopy, to reveal the first example of a Re(I)-dppz complex with a charge separated lowest-lying excited state.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Kinetics
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Molecular Conformation
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Molecular Structure
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Organometallic Compounds / chemistry*
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Photochemistry
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Physical Phenomena
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Physics
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Rhenium / chemistry*
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Spectrophotometry, Infrared
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Spectrophotometry, Ultraviolet
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Spectroscopy, Fourier Transform Infrared
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Time Factors
Substances
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Organometallic Compounds
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Rhenium