Role of surface plasmons in the decay of image-potential States on silver surfaces

Phys Rev Lett. 2002 Aug 26;89(9):096401. doi: 10.1103/PhysRevLett.89.096401. Epub 2002 Aug 8.

Abstract

The combined effect of single-particle and collective surface excitations in the decay of image-potential states on Ag surfaces is investigated, and the origin of the long-standing discrepancy between experimental measurements and previous theoretical predictions for the lifetime of these states is elucidated. Although surface-plasmon excitation had been expected to reduce the image-state lifetime, we demonstrate that the subtle combination of the spatial variation of s-d polarization in Ag and the characteristic nonlocality of many-electron interactions near the surface yields surprisingly long image-state lifetimes, in agreement with experiment.