Abstract
[reaction: see text] The reduction of beta-amino ketones with samarium(II) iodide has been investigated. Either the syn or anti 1,3-amino alcohols can be obtained as the major product due to a divergence in selectivity with different N-protecting groups.
Publication types
-
Research Support, U.S. Gov't, P.H.S.
MeSH terms
-
Amines / chemistry
-
Amino Alcohols / chemical synthesis*
-
Anti-Bacterial Agents / chemical synthesis
-
Biological Factors / chemical synthesis
-
Hydrogenation
-
Iodides / chemistry
-
Ketones / chemistry*
-
Molecular Structure
-
Samarium / chemistry
-
Stereoisomerism
Substances
-
Amines
-
Amino Alcohols
-
Anti-Bacterial Agents
-
Biological Factors
-
Iodides
-
Ketones
-
Samarium
-
samarium diiodide