An extended chain structure formed by covalently linking polyoxovanadate cages with tetrahedral six rings

Chem Commun (Camb). 2001 Dec 7:(23):2472-3. doi: 10.1039/b108303a.

Abstract

The compound Cs10.5[(V16O40)(Si4.5V1.5O10)].3.5H2O is the first example of an extended structure in which a polyoxometallate anion is linked by an extended tetrahedral unit.