An acid-catalyzed macrolactonization protocol

Org Lett. 2002 Oct 17;4(21):3743-5. doi: 10.1021/ol026726c.

Abstract

[reaction: see text] An efficient macrolactonization protocol devoid of any base was developed derived from the use of vinyl esters in transesterification. Subjecting a hydroxy acid and ethoxyacetylene to 2 mol % [RuCl(2)(p-cymene)](2) in toluene followed by addition of camphorsulfonic acid or inverse addition provided macrolactones in good yields.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Acids / chemistry*
  • Catalysis
  • Lactones / chemistry*

Substances

  • Acids
  • Lactones