Controlled fabrication of cross-linked nanoparticles/polymer composite thin films through the combined use of surface-initiated atom transfer radical polymerization and gas/solid reaction

Jia-Yu Wang; Wei Chen; An-Hua Liu; Guang Lu; Gang Zhang; Jun-Hu Zhang; Bai Yang

doi:10.1021/ja027795p

Controlled fabrication of cross-linked nanoparticles/polymer composite thin films through the combined use of surface-initiated atom transfer radical polymerization and gas/solid reaction

J Am Chem Soc. 2002 Nov 13;124(45):13358-9. doi: 10.1021/ja027795p.

Authors

Jia-Yu Wang¹, Wei Chen, An-Hua Liu, Guang Lu, Gang Zhang, Jun-Hu Zhang, Bai Yang

Affiliation

¹ Key Lab of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130023, PR. China.

PMID: 12418868
DOI: 10.1021/ja027795p

Abstract

A promising strategy for the controlled synthesis of inorganic/polymeric nanocomposites may be sustained by fabricating cross-linked PbS nanoparticles/polymer composite thin films through combining surface-initiated atom transfer radical polymerization (ATRP) and gas/solid reaction. The introduction of Pb ions through the extension of surface-initiated ATRP to the monomers containing metal ions provides an opportunity for generating nanoparticles on the substrate.