Preparation and reactivity of O2-sulfonated diazeniumdiolates

J Org Chem. 2003 Jan 24;68(2):656-7. doi: 10.1021/jo026656n.

Abstract

We report the facile preparation of O2-sulfonated diazeniumdiolates and mechanistic investigation of their reactions with representative nucleophiles. This new class of compounds extends the range of O2-substituted diazeniumdiolates available for potential applications in research and medicine.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, P.H.S.

MeSH terms

  • Alkanesulfonates / chemical synthesis*
  • Alkanesulfonates / chemistry*
  • Azo Compounds / chemical synthesis*
  • Azo Compounds / chemistry*
  • Catalysis
  • Molecular Structure
  • Oxygen / chemistry*
  • Tosyl Compounds / chemistry

Substances

  • Alkanesulfonates
  • Azo Compounds
  • Tosyl Compounds
  • diazeniumdiolate
  • Oxygen