Synthesis and electrochemical properties of novel tetrametallic macrocyclic Fischer carbene complexes

Org Lett. 2003 Apr 17;5(8):1237-40. doi: 10.1021/ol0342094.

Abstract

[reaction: see text] Metallomacrocyclic compounds can be easily prepared by 1,4-addition of diamines to alpha,beta-unsaturated Fischer bis-carbene templates. This method allows the preparation of a new family of homo- and heterotetrametallic compounds having macrocyclic cyclophanic structures.