A free radical initiated optically active vinyl polymer with memory of chirality after removal of the inducing stereogenic center

Chem Commun (Camb). 2003 Apr 21:(8):974-5. doi: 10.1039/b212916g.

Abstract

Free radical polymerization of (+)-2,5-bis[4'-((S)-2-methylbutyloxy)phenyl]styrene yields a chiral polymer with memory of optical activity after the initial stereogenic center in the side group of the monomer is chemically removed.