Functional restoration of the Ca2+-myristoyl switch in a recoverin mutant

J Mol Biol. 2003 Jul 4;330(2):409-18. doi: 10.1016/s0022-2836(03)00581-3.

Abstract

Recoverin is a neuronal calcium sensor protein that plays a crucial role in vertebrate phototransduction. It undergoes a Ca(2+)-myristoyl switch when Ca(2+) binds to its two functional EF-hand motifs (EF-hands 2 and 3), each present in one of recoverin's two domains. Impairment of Ca(2+)-binding in recoverin leads to a disturbance of the Ca(2+)-myristoyl switch and loss of its regulatory properties, i.e. inhibiton of rhodopsin kinase. We have engineered recoverin mutants with either of the two functional EF-hands disabled, but with a functional Ca(2+)-binding site in EF-hand 4. While a defect in EF-hand 2 could not be rescued by the additional EF-hand 4, the impairment of EF-hand 3 was powerfully compensated by Ca(2+)-binding to EF-hand 4. For example, the myristoylated form of the latter mutant bound to membranes in a Ca(2+)-dependent way and was able to inhibit rhodopsin kinase in a way similar to that of the wild-type protein. Thus, for recoverin to undergo a Ca(2+)-myristoyl switch, it is necessary and sufficient to have either of the two EF-hands in the second domain in a functional state. On the basis of these results and inspection of published three-dimensional structures of recoverin, we propose a model highlighting the mutual interdependence of sterical configurations in EF-hands 3 and 4 of recoverin.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Binding Sites / genetics
  • Calcium / metabolism*
  • Calcium-Binding Proteins / chemistry
  • Calcium-Binding Proteins / genetics*
  • Calcium-Binding Proteins / metabolism*
  • Cattle
  • Eye Proteins*
  • G-Protein-Coupled Receptor Kinase 1
  • Hippocalcin
  • In Vitro Techniques
  • Kinetics
  • Lipoproteins*
  • Models, Molecular
  • Mutation
  • Myristic Acid / metabolism*
  • Nerve Tissue Proteins*
  • Protein Conformation
  • Protein Engineering
  • Protein Kinase Inhibitors
  • Protein Kinases*
  • Recombinant Proteins / chemistry
  • Recombinant Proteins / genetics
  • Recombinant Proteins / metabolism
  • Recoverin
  • Rod Cell Outer Segment / metabolism
  • Vision, Ocular

Substances

  • Calcium-Binding Proteins
  • Eye Proteins
  • Lipoproteins
  • Nerve Tissue Proteins
  • Protein Kinase Inhibitors
  • Recombinant Proteins
  • Myristic Acid
  • Recoverin
  • Hippocalcin
  • Protein Kinases
  • G-Protein-Coupled Receptor Kinase 1
  • Calcium